Masters Degrees (Geology)

Permanent URI for this collectionhttps://hdl.handle.net/10413/6622

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Mineralogy and geochemistry of clay sediments in pans of the Northern Cape Province, South Africa.
(2010) Roelofse, Tiani.; Cloete, M.; Dunlevey, John N.
This thesis reports the results of a mineralogical and geochemical study of pans situated in the Northern Cape Province with special emphasis on the clay minerals. From east to west the depth and size of the pans increase and associated with this increased maturity the abundance of salt (halite and thenardite) and the quantity of green sediment are also enhanced. Chemically the sediments are dominated by SiO2 that also dilutes Fe2O3, K2O, Na2O, Al2O3 and MgO (when associated with dolomite) concentrations. Authigenic calcite, dolomite, analcime and loughlinite (Na-sepiolite) occur in some of the pans to the west and FTIR spectrometry indicates that all the pans host glauconite and/or celadonite. However, smectite, illite/smectite interstratification, kaolinite and/or chlorite and loughlinite only occur in some pans. The glauconite and/or celadonite does not occur as discrete mineral grains, but forms part of the fine-grained matrix common to all of the pans and no evidence of any precursor minerals were observed. The pan environment appears to present a closed, saline setting that is conducive for the direct precipitation of a mica with a chemical composition between that of glauconite and celadonite. The influence of the water-table on the formation of the glauconite and/or celadonite appears to be significant, as the highest abundance of salt is invariably associated with the position in the profile where the sediment appears to reach its most intense green colour. In the case of Koi Pan, the celadonite component of the solid solution seems to increase as the green colour intensifies. Loughlinite in Koi Pan and Brak Pan sediments also appear to be authigenic and it is suggested that it forms after precipitation of low Mg calcite that leads to Mg enrichment of the system and consequent sepiolite formation associated with minor dolomite. Thermoluminescence ages obtained from the Koi Pan sediment range between 37ka and 48ka before present at a depth of ~120cm below the surface, while for Brak Pan, at roughly the same depth, an age of between 110ka and older than 150ka before present was obtained. This may suggest different sedimentation rates in the pans or much younger ages and thus faster formation of glauconite and/or celadonite in Koi Pan since it is suggested that the mineral is authigenic.
Mineralogy and geochemistry of detrital rutile from the Sibaya Foundation, KwaZulu-Natal.
(2002) Bramdeo, Siksha.; Dunlevey, John N.
Rutile, although not a major component of detrital heavy mineral deposits, is a valuable source of titanium oxide. Theoretically rutile is pure titanium dioxide (TiO2) and should form white or colourless tetragonal crystals with a density of 4.25gm/ml. However, natural rutile although tetragonal, displays a variety of colours ranging from red through brown to black, yellow or blue, variable density between 4.23 to 5.50g/ml as well as a range in the magnetic susceptibility and electrical conductivity. In addition to these variations exhibited by natural rutile, samples from detrital heavy mineral deposits normally contain, in addition to homogenous grains, composite grains, in which rutile is intergrown with one or more mineral species, commonly quartz, feldspar and ilmenite. The Sibaya Formation, like most detrital heavy mineral deposits, has a polymictic source, and as such contains rutile grains formed in many different chemical environments. Homogenous rutile grains display a chemical variation with a preference for the select few elements, which are compatible with the rutile cyrstallographic structure. The ions that substitute for titanium (Ti4+) in the crystal lattice are a reflection of chemical environment in which the crystal formed. The size and charge of the Ti4 + ion greatly restricts the species that may enter the rutile crystal lattice, with Sb3 +, V3 +, Fe3 +, Cr3 +, Sn4 +, M04+, W4+, Mn4+, 8i5+, Nb5+, Ta5 +, Sb5 +, V5 +, being theoretically compatible with the size and charge of the Ti4+ ion. Electron microprobe analysis of detrital rutile grains from the Sibaya Formation, KwaZulu-Natal show that elements, Nb5 +, Ta5+, A13+, Zr4+, Si4+, Fe3+, Cr3 +, and V5 +, commonly substitute for the Ti4 + ion. However, Sb3+, Sn4+, M04+, W4 + and 8i5 + were not present at detectable levels implying that the provenance area is not enriched in these elements. Although the high Fe3+ values were expected in the rutile grains, as Fe3 + is common in many rocks, the high Si4+ values encountered were not expected, as Si4 + is not normally compatible with Ti4 + ion, as noted by their distinct separation in rutilated quartz. The anomalous Si4 + content of certain grains suggests that within the provenance area rutile bearing rocks formed under unusual conditions, such as high pressure, temperature and silicon activity where the high charge density of the Si4 + ion would favour the inclusion of Si4 + into the rutile lattice. The chemical variation of the rutile grains causes significant variation in the magnetic susceptibility and electrical conductivity, and thus has marked effects on mineral processing, which relies heavily on magnetic and electrostatic separation techniques. The data presented indicates that individual homogenous rutile grains displays significant range of chemical composition, commonly containing other oxides from a fraction of a weight percent to well over 10wt%. Data plots of TiO2, FeO and 'other' oxides (Nb2O5, Ta2O5, A12O3, ZrO2, SiO2, Cr2O3 and V2O3), showed that many of the more magnetic rutile grains appeared to be FeO enriched and contained a higher proportion of 'other' oxides. However, some grains that just had higher proportions of 'other' oxides and a lower FeO content were also magnetic. Thus magnetic susceptibility although strongly influenced by the presence of FeO, can also be enhanced by the substitutions of other oxides. The vast majority of rutile grains from the electrostatic fractions were relatively TiO2 pure, and contained low concentrations of 'other' oxides. However, some grains did have slightly enhanced SiO2 and V2O3 concentrations, which appear to enhance the conductivity of the grains. Four main colour groups were differentiated from the population of rutile grains from the Sibaya Formation, these being, reddish brown, black, blue and yellow. No single oxide seemed solely responsible for the colour of rutile grains. However, the red rutile grains had a slightly but significantly higher Cr2O3 and Nb2O5 content, whereas black rutile grains appeared to be V2O3 and Nb2O5 enriched. The blue colour of rutile grains appears to be influenced by a combination of SiO2, Al2O3 and Nb2O5 substitutions. The yellow rutile grains had slightly enhanced FeO and Nb2O5 concentrations. Although these differences are very small, trace quantities of certain elements and different combinations of elements can have a strong effect on colour. Apart from Fe3+, no single element; appears to be solely responsible for variations noted in the physical characteristics (magnetic susceptibility, electrostatic conductivity and colour) of homogenous rutile grains from the Sibaya Formation. However a combination of substituting elements appears to influence magnetic susceptibility and electrical conductivity. An enhanced Fe3+ content normally increases the magnetic susceptibility although combinations of other elements may have the same effect on Fe3+ poor grains. In general terms, the purer the rutile grain, the more likely it is, to be non-magnetic and conductive. Substitutions of 'other' oxides appear to decrease the conductivity of rutile grains. The relationship between grain colour and chemistry is also not very clear, verifying the widely held view that grain colour is often the result of more than just mineral chemistry.
The petrology and geochemistry of the karoo sequence basaltic rocks in the Natal Drakensberg at Sani Pass.
(1992) Ramluckan, Vijay Rajlal.; Dunlevey, John N.; Mitchell, A. A.
The Sani Pass in the Natal Drakensberg is situated in the north-eastern sector of the Lesotho Highlands which forms a major Karoo-age basaltic massif in the Karoo Igneous Province. The volcanic section exposed in the pass is approximately 800m thick, and comprises a succession of regularly stratified, massive and amygdaloidallavas which were extruded mainly by fissure-type eruptions. Dolerite dykes, which now occupy thefissures,form a network ofpredominantly NE-SW and NW-SE trending topographic features. During post-eruption cooling hydrothermal solutions percolated through the volcanic succession and produced an amygdale zonation which was controlled predominantly by ambientpressure and temperature conditions. An original maximum thickness of 1 820m of the volcanic succession has therefore been estimated and an average fossil geothermal gradient of 111° C/km is conceived to have persisted during amygdale formation. New electron microprobe data are presented for the silicate phases in the Sani Pass basalts and dolerites. These data do not effectively separate the Sani Pass volcanic succession into different geochemical units. Microprobe analysesfor olivine, albeit limited, are in the forsterite range and indicate that a proportion of olivine in the high-MgO basalts is due to cumulus enrichment. The pyroxenes are predominantly augite and minor pigeonite, with some ofthe augites displaying a tholeiitic trend similar to that recognised at Skaergaard. Plagioclase is mainly in the labradorite to bytownite range, the phenocrysts being slightly enriched in anorthite compared to the groundmass. The use ofwhole-rock geochemistry for 67 basalts and 8 dolerites has permitted the recognition of five geochemically distinct magma types, namely, the Giant's Cup, Agate Vale, Sakeng, Mkhomazana and the Phinong. The Phinong basalts comprise the upper two-thirds ofthe volcanic succession and although are generally homogeneous, there is a slight tendency for the more evolved rocks to be found higher up in the stratigraphic sequence. The remaining magma types precede the Phinong succession and are generally enriched in silica and have higher Zr/Nb and lower PfZr ratios than the Phinong basalts. Within the pre-Phinong succession the Giant's Cup basalts are generally depleted in the compatible elements, while the overlying Agate Vale basalts are enriched in incompatible elements. Except for a marginally lower Na20 and Sr content, the chemistry ofthe Sakeng basalts is variable, generally overlapping with the other magma types. The Mkhomazana basalts are slightly enriched in MgO, Ni, Cr and Sc compared to all other pre-Phinong basalts. The dolerites in the area adjacent to the Sani Pass are geochemically similar to the Phinong basalts. The Phinong magma type is considered to be equivalent to the Lesotho magma type, based on their geochemical and stratigraphical similarities. In terms ofdiscriminant diagrams the Giant's Cup, Sakeng and Mkhomazana basalts generally show some compositional overlap with the Phinong, or plot in incoherentfields, but the Agate Vale basalts are distinctly different and might indicate a new magma type within the Karoo Central area. Broad compositional overlap between the Phinong basalts and those preserved at Kirwan and Heimefrontfjella, Antarctica, indicates juxtaposition of Antarctica along the southern African east coast in a reconstructed Gondwanaland. Petrogenesis of the Sani Pass basalts has been examined in terms of alteration, open and closed system fractional crystallization, partial melting procesess and a heterogeneous source. Although limited alteration and conduit contamination have occurred, the most feasible mechanism responsible for the geochemical variation lies in the existance ofinhomogeneities in the upper mantle at the time ofgeneration of the Sani Pass magmas.

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Browsing Masters Degrees (Geology) by Author "Dunlevey, John N."