Masters Degrees (Geology)

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The petrology, geochemistry and classification of the Bien Venue massive sulphide deposit, Barberton mountain land.
(1990) Murphy, Philip William.; Harwood, Anthony.; Kerr, Alan.
The Bien Venue massive sulphide deposit is associated with a felsic volcanic succession developed in the north-eastern part of the Barberton Greenstone Belt, Eastern Transvaal. The deposit is situated 8km east-north-east of Louw's Creek between the Lily Syncline to the south and the Stentor Pluton to the north. The stratigraphy of the Onverwacht, Fig Tree and Moodies Groups in the vicinity of the deposit is poorly documented, and the exact stratigraphic position of the host felsic volcanics is not known. They are tentatively correlated with the felsic volcanics from the Theespruit Formation, Onverwacht Group. The felsic volcanics have undergone low-grade greenschist facies metamorphism and occur as quartz-sericite schists. Detailed petrography enables sub-division of the volcanic succession into distinct units. A lapilli metatuff unit hosts the base metal and precious metal mineralisation. The sulphides are best developed in the upper part of this unit, together with intercalated barite-rich horizons and cherts. A series of structural events have modified the attitude of the lithological units and disrupted the continuity of the orebody. The orebody comprises stratabound lenses of massive to semi-massive and often banded sulphides, as well as disseminated sulphide mineralisation. The dominant base metal mineralogy consists of pyrite, sphalerite, chalcopyrite, galena and tennantite. Native silver and various copper-silver sulphides are also associated with the base metal sulphides. A vertical zonation of the mineralisation exists, from pyrite-chalcopyrite-rich ore in the footwall, to pyrite - chalcopyrite-sphalerite-galena-barite-rich ore towards the hanging wall. Geochemical studies indicate that the Bien Venue lithologies are rhyolitic to rhyodacitic in composition and show a calc-alkaline affinity. The mobility of some elements at Bien Venue has been clearly demonstrated. This is believed to be associated with hydrothermal alteration that has led to SiO2 and MgO enrichment, as well as K2O depletion, in the wall rocks of the deposit. The geological setting and nature of the mineralisation at Bien Venue suggest that it is an example of a volcanogenic exhalative sulphide deposit. In terms of the classification scheme suggested by Hutchinson (1973, 1980), Bien Venue would best be described as a Primitive type deposit that contains barite.
The mineralogy and related geology of the Albert Silver Mine, Bronkhorstspruit, Transvaal
(1970) Champion, Alfred Timothy.
The Albert Silver mine is situated on the farm Roodepoortjie, 32 kilometres north of Brorikhorstspruit in the Transvaal. The deposit forms the largest of a number of sub-parallel quartzhematite lodes accompanied by sulphide mineralization and is accompanied by an extensive alteration zone along its northern flank.
Characterisation of geotechnical, geochemical and metallurgical properties for mine-to-mill optimisation at Sandsloot open pit platinum mine, South Africa
(2008) Walker, Shonagh.
Sandsloot open pit mine extracts platinum, copper and nickel from the Platreef orebody in the Northern Limb of the Bushveld Complex. At present, it is the world's largest open pit platinum mine, but it is one of the smaller of six pits to be mined in this area by Potgietersrust Platinums Limited (PPRust). As mining progresses and the mine operations expand, sound knowledge of the subsurface ground, the orebody properties and their performance in the processing plant is imperative. An accurately characterised orebody, in terms of its geotechnical, geochemical and metallurgical properties, will facilitate the development of appropriate and cost effective mining practices and processing plant design. It will improve the prediction and performance of materials in each of the steps involved in converting the orebody rock mass into a concentrate /marketable product, which ultimately leads to mine-to-mill optimisation. This dissertation has focused on the geotechnical and metallurgical strength properties of the Platreef orebody at Sandsloot; the geochemical properties of the various lithologies and defined for each orebody rock type the associations and correlations within and between these properties. The petrography of the orebody material was studied to identify and classify the rock types. A rigorous testing programme was conducted and an extensive database of petrographic, geotechnical, geochemical and metallurgical information was assembled. The corresponding results within and across the different studies were grouped together and statistical analysis and interrogation of the data sets were performed. The research identified diverse rock types with contrasting physical properties in the Sandsloot open pit orebody. For each of the rock types the distinguishing characteristics and the variations in properties were identified. Significant differences and relationships between rock types for each property were assessed for predictability in mining. Statistical associations and correlations between the properties of each study were defined and models for predicting strength and rock type were developed.
The mineralogy, petrology and PGE geochemistry of the UG2 cyclic unit at Lebowa Platinum mine (ATOK), North-Eastern Bushveld complex.
(2008) Fitzhenry, Clifford.
This project is an investigation of the UG2 cyclic unit of the Upper Critical Zone at Lebowa (Atok)
A combined sedimentological-mineralogical study of sediment-hosted gold and uranium mineralization at Denny Dalton, Pongola Supergroup, South Africa.
(2009) Hicks, Nigel.; Hofmann, Axel.
The ~2.98 - 2.87 Ga Pongola Supergroup in South Africa is subdivided into the lower volcano-sedimentary Nsuze Group, and the upper sedimentary Mozaan Group, the latter comprising a several kilometres thick succession of fluvial to shallow marine sandstones and shales. Thin beds of gold and uranium-bearing conglomerates are locally present in the Mandeva Formation near the base of the Mozaan Group and have been mined at Denny Dalton in northern KwaZulu-Natal. The style of mineralization strongly resembles that of the Witwatersrand goldfields, however appears to be of low grade and limited tonnage. The ~1 m thick basal conglomerate, the “Mozaan Contact Reef” (MCR, herein referred to as CG 1), at Denny Dalton hosts erratic gold and uranium mineralization. The conglomerate is laterally discontinuous and occupies east-northeast trending scour channels. Polymict, matrix-supported conglomerates are common, while clast-supported conglomerates are rare. Well rounded, pebble to cobble-sized clasts of vein quartz and chert are hosted in a sandy matrix of quartz, pyrite and sericite. Where mineralized, the CG 1 hosts abundant rounded pyrite grains, interpreted as detrital in origin, with subordinate U-bearing minerals, such as brannerite and uraniferous leucoxene. Rounded detrital pyrite occurs in three phases, compact, porous and radial. Gold forms inclusions within massive pyrite grains, which are concentrated in shoots associated with the basal parts of the channel scours. SEM-EDX results, as well as the high reflectivity of the gold show a high Ag content, indicative of a primary origin for the gold within the pyrite grains. Uranium within CG 1 is hosted primarily as secondary inclusions of uranium within black chert pebbles within the basal cobble-sized regions of the conglomerate. Geochemical comparison of the chert pebbles at Denny Dalton with similar chert from the Nondweni Greenstone Belt indicates that the uranium is secondary in origin as no U anomalies occur in the Nondweni chert. Geochemical and SEM analysis of the uppermost conglomerate (CG 4) indicate the presence of uraninite and coffinite within the uppermost horizon as both fillings of voids within, and coatings on, detrital pyrite grains. Palaeocurrent data indicate a likely source terrain for the detrital material to the west of the inlier. This orientation, as well as differing mineralogical and sedimentological aspects between the Mandeva Formation and the correlative Sinqeni Formation within the main Pongola basin, indicate a separate and more proximal provenance for the auriferous conglomerates of the White Umfolozi Inlier. The Mandeva Formation is a fluvial to shallow marine sequence that has been affected by cyclic sea-level changes. The basal conglomerates of the Denny Dalton Member were deposited in a proximal braided alluvial plain environment. The conglomerates fine upwards into trough cross-bedded quartz arenites which appear to have been deposited as shallow marine sands in a shoreface environment. They are overlain with a sharp contact by a laterally extensive unit of polymictic conglomerate which represents a transgressive ravinement surface within the wave zone and marks the onset of a major marine transgression into the Pongola basin. The conglomerate is overlain by massive grits and coarse-grained quartz arenite. This unit is overlain with a sharp and locally sheared contact by shales and subordinate banded iron formation which can be traced into other parts of the Pongola basin and indicates continued rapid transgression onto large parts of the Kaapvaal Craton with deeper marine, sub-storm wave base sediments being deposited in quiet-water environments on a sediment-starved shelf. The heavy mineral assemblage as well as bulk geochemical data is consistent with a granitoid-greenstone source terrain for the conglomerates and sandstones. The geochemical composition of chert pebbles from the CG 1 is similar to the composition of cherts present in the Nondweni Greenstone Belt that is situated ~30 km west of the White Umfolozi Inlier. Multiple sulphur isotope (ä34S, ä33S) values for detrital pyrite from the MCR are consistent with an origin from mantle-like rocks, such as hydrothermal sulphide-quartz veins in a granitoid-greenstone setting. Palaeocurrent, mineralogical and geochemical data all point to a likely granitoid-greenstone provenance to the west of the White Umfolozi Inlier.
The lithostratigraphy and petrogenesis of the Nsuze group northwest of Nkandla, Natal.
(1984) Groenewald, Peter Bruce.
The volcanic and sedimentary Nsuze Group constitutes the lower part of the
Mineralogy and geochemistry of detrital rutile from the Sibaya Foundation, KwaZulu-Natal.
(2002) Bramdeo, Siksha.; Dunlevey, John N.
Rutile, although not a major component of detrital heavy mineral deposits, is a valuable source of titanium oxide. Theoretically rutile is pure titanium dioxide (TiO2) and should form white or colourless tetragonal crystals with a density of 4.25gm/ml. However, natural rutile although tetragonal, displays a variety of colours ranging from red through brown to black, yellow or blue, variable density between 4.23 to 5.50g/ml as well as a range in the magnetic susceptibility and electrical conductivity. In addition to these variations exhibited by natural rutile, samples from detrital heavy mineral deposits normally contain, in addition to homogenous grains, composite grains, in which rutile is intergrown with one or more mineral species, commonly quartz, feldspar and ilmenite. The Sibaya Formation, like most detrital heavy mineral deposits, has a polymictic source, and as such contains rutile grains formed in many different chemical environments. Homogenous rutile grains display a chemical variation with a preference for the select few elements, which are compatible with the rutile cyrstallographic structure. The ions that substitute for titanium (Ti4+) in the crystal lattice are a reflection of chemical environment in which the crystal formed. The size and charge of the Ti4 + ion greatly restricts the species that may enter the rutile crystal lattice, with Sb3 +, V3 +, Fe3 +, Cr3 +, Sn4 +, M04+, W4+, Mn4+, 8i5+, Nb5+, Ta5 +, Sb5 +, V5 +, being theoretically compatible with the size and charge of the Ti4+ ion. Electron microprobe analysis of detrital rutile grains from the Sibaya Formation, KwaZulu-Natal show that elements, Nb5 +, Ta5+, A13+, Zr4+, Si4+, Fe3+, Cr3 +, and V5 +, commonly substitute for the Ti4 + ion. However, Sb3+, Sn4+, M04+, W4 + and 8i5 + were not present at detectable levels implying that the provenance area is not enriched in these elements. Although the high Fe3+ values were expected in the rutile grains, as Fe3 + is common in many rocks, the high Si4+ values encountered were not expected, as Si4 + is not normally compatible with Ti4 + ion, as noted by their distinct separation in rutilated quartz. The anomalous Si4 + content of certain grains suggests that within the provenance area rutile bearing rocks formed under unusual conditions, such as high pressure, temperature and silicon activity where the high charge density of the Si4 + ion would favour the inclusion of Si4 + into the rutile lattice. The chemical variation of the rutile grains causes significant variation in the magnetic susceptibility and electrical conductivity, and thus has marked effects on mineral processing, which relies heavily on magnetic and electrostatic separation techniques. The data presented indicates that individual homogenous rutile grains displays significant range of chemical composition, commonly containing other oxides from a fraction of a weight percent to well over 10wt%. Data plots of TiO2, FeO and 'other' oxides (Nb2O5, Ta2O5, A12O3, ZrO2, SiO2, Cr2O3 and V2O3), showed that many of the more magnetic rutile grains appeared to be FeO enriched and contained a higher proportion of 'other' oxides. However, some grains that just had higher proportions of 'other' oxides and a lower FeO content were also magnetic. Thus magnetic susceptibility although strongly influenced by the presence of FeO, can also be enhanced by the substitutions of other oxides. The vast majority of rutile grains from the electrostatic fractions were relatively TiO2 pure, and contained low concentrations of 'other' oxides. However, some grains did have slightly enhanced SiO2 and V2O3 concentrations, which appear to enhance the conductivity of the grains. Four main colour groups were differentiated from the population of rutile grains from the Sibaya Formation, these being, reddish brown, black, blue and yellow. No single oxide seemed solely responsible for the colour of rutile grains. However, the red rutile grains had a slightly but significantly higher Cr2O3 and Nb2O5 content, whereas black rutile grains appeared to be V2O3 and Nb2O5 enriched. The blue colour of rutile grains appears to be influenced by a combination of SiO2, Al2O3 and Nb2O5 substitutions. The yellow rutile grains had slightly enhanced FeO and Nb2O5 concentrations. Although these differences are very small, trace quantities of certain elements and different combinations of elements can have a strong effect on colour. Apart from Fe3+, no single element; appears to be solely responsible for variations noted in the physical characteristics (magnetic susceptibility, electrostatic conductivity and colour) of homogenous rutile grains from the Sibaya Formation. However a combination of substituting elements appears to influence magnetic susceptibility and electrical conductivity. An enhanced Fe3+ content normally increases the magnetic susceptibility although combinations of other elements may have the same effect on Fe3+ poor grains. In general terms, the purer the rutile grain, the more likely it is, to be non-magnetic and conductive. Substitutions of 'other' oxides appear to decrease the conductivity of rutile grains. The relationship between grain colour and chemistry is also not very clear, verifying the widely held view that grain colour is often the result of more than just mineral chemistry.
Rock mass rating and slope stability analysis of quarry faces within the dywka [i.e. dwyka] tillite of KwaZulu-Natal.
(2002) Kujawa, Thomas.; Jermy, Colin A.
Dwyka tillite quarries in the Province of KwaZulu-Natal have shown remarkable stable slopes faces even though some of them were quarried over 30 years ago. This can be attributed to their resistance to weathering, the high degree of joint surface roughness, the general lack of any joint infill and the limonitic staining found on most weathered joint surfaces. The latter appears to increase joint roughness. The high percentages of joints terminating within the rock mass or against other discontinuities as well as their low persistence results in a high degree of joint interlocking. These are shown to be very important factors contributing to the overall slope stability. Detailed discontinuity surveys were carried out at five different quarries located throughout the KwaZulu-Natal region. Only three of these quarries are presently being quarried. This allowed the study and comparison of joint and slope stability characteristics for both the older, more weathered rock faces and those of the recently quarried, and thus fairly unweathered rock faces. Joint orientation data from the various sites show that two to three sets of high angle joints and one low angle joint set are common. The potential of wedge and planar failure is therefore very high. The steeply dipping discontinuities also promote the potential for flexural toppling failure and this was noted in several of the quarry faces. Recognised geotechnical techniques and computer models were used to establish potential modes of failure and to estimate factors of safety. Wedge failure, at partially saturated and saturated conditions, was identified as being the main source of potential slope instability on the quarry rock faces. The quality of the rock mass of each slope was also classified according to various rock mass classification systems. The rock mass quality generally was rated as being 'fair' to 'good', meaning that slopes are partially stable to stable. The results of each rating system were also compared.
The geology and rock mass quality of the Cenozoic Kalahari Group, Nchwaning Mine Northern Cape.
(2002) Puchner, Richard A.; Watkeys, Michael Keith.; Jermy, Colin A.; Maud, Rodney.
With the extension of the Nchwaning Mine shaft complex in the Northern Cape Province, various geological and geotechnical complications needed to be identified in order to ensure correct use of tunnelling methods and support techniques. An understanding of the geological history of the area and the resulting geotechnical nature was important in defining the rock mass quality ahead of shaft development. A total of 12 geotechnical boreholes were drilled, and an additional 18 old boreholes revisited to accurately detennine the stratigraphy, geological structure and associated weathering effects. Various soils and rock testing helped quantify the materials encountered. Sands of the Gordonia Fonnation form the surface cover of this area, and together with the weathered calcrete, calc-arenite, conglomerate and clay, they form part of the Cenozoic Kalahari Group. The 30m thick basal unit of red clay is common throughout this region. This silty clay material is problematic in that it is expansive and hygroscopic. The clay unit rests unconformably on folded, faulted and highly weathered shale of the Proterozoic Lucknow and Mapedi Formations of the Olifantshoek Supergroup. Unconformably below this sequence lies the manganiferous ore deposits of the Hotazel Member, which is contained within the Voelwater Formation of the Griqualand West Supergroup. For the development of the decline shaft through the Gordonia Formation a box cut was excavated to a depth of 25m. The anticipated poor geotechnical conditions for a further 125m below the Gordonia sands called for high quality permanent tunnel support in the upper weathered horizons. Barton's Q-analysis was adopted as a recognized tunnelling quality index to predict and quantify the rock mass characteristics ahead of the shaft. The highly variable and generally low Q-values from borehole core analysis indicated that precast tunnel lining be used for 800m (at 11.5°) through the entire weathered Cenozoic sequence and into the weathered shales immediately below the Red Clay.
The physical volcanology and geochemistry of the Nsuze group, Pongola supergroup, of northern KwaZulu-Natal and southeastern Mpumalanga.
(2003) Grant, Claire Elizabeth.; Wilson, Allan H.
The Nsuze Group forms the lower, predominantly volcanic succession of the Pongola Supergroup. The 2.9Ga Nsuze Group outcrops in southeastern Mpumalanga, northern KwaZulu-Natal and Swaziland. The volcanic rocks of the Nsuze Group are basalts, basaltic andesites, andesites, dacites and rhyolites preserved as both lava and pyroclastic deposits. The oldest volcanic sequence of the Nsuze Group is the basaltic Wagondrift Formation. The younger Bivane Subgroup represents the main volcanic component of the Nsuze Group. The White River Section represents a complex volcanic history of magma storage, fractionation, and eruption, supplied by a multi-level system of magma chambers. The basaltic and basaltic andesite rocks of the White Mfolozi Inlier represent the steady and non-violent eruption of lavas from related volcanic centres. The Nsuze Group rocks have been metamorphosed by high heat flow burial metamorphism to lower greenschist facies. Geochemically, elements display well-defined fractionation trends, with evident sub-trends within each phase group of samples. These sub-trends are related to the fractionation of key minerals, in particular plagioclase. The REE patterns show that evolution of magma was largely controlled by the fractionation of plagioclase. All REE patterns show LREE enrichment relative to the HREE. The Wagondrift Formation was derived from a more depleted source than the younger Bivane Subgroup volcanic rocks and exhibits a within-plate tectonic signature. The volcanic rocks of the Bivane Subgroup in the White River Section and the White Mfolozi Inlier are geochemically similar. The volcanic rocks of the Bivane Subgroup of both the White River Section and the White Mfolozi Inlier have a subduction zone tectonic signature, in particular a Ta-Nb negative anomaly. Tectonic discrimination diagrams suggest an enriched source related to a continental-arc setting. The geochemistry suggests an eclogitic source for the Nsuze Group volcanic rocks. The formation of eclogite in the mantle requires subduction of basaltic material. Archaean models for subduction-like processes include decoupling of oceanic crust and subsequent underplating of the continental lithosphere, and low-angle subduction which minimises the effect of the mantle wedge. It is possible that a combination of these processes resulted in an enriched eclogitic source for the magmas of the Nsuze Group.
Seismic stratigraphy of the northern KwaZulu-Natal upper continental margin.
(1998) Shaw, Michael John.; Mason, Tom R.; Watkeys, Michael Keith.; Ramsay, Peter John.
This study presents the interpretation of Edo-Western and Sparker seismic geophysical data acquired on the northern KwaZulu-Natal upper continental margin by various organisations since 1981. Five seismic sequences are recognised and these are traceable across the entire length of the study area. The oldest is interpreted as a late Cretaceous marine sequence (Sequence A), probably the offshore equivalent of the St. Lucia Formation exposed onshore. This sequence is overlain by a progradational, probable late Tertiary shelf sequence (Sequence B) onlapping in places against the underlying marine sequence. The outer portion of this sequence on the upper continental slope is characterised by complicated reflection termination patterns indicating the possible presence of discreet sequences within this shelf and slope unit. These shelf and slope sediments are overlain by a thin (less than 20m) reworked and eroded Pleistocene shelf unit (Sequence C), itself overlain by linear Pleistocene aeolianites (Sequence D) in places. The youngest sequence observed is the Holocene unconsolidated sediment wedge (Sequence E) on the inner shelf, attaining thicknesses of greater than 20m in places. The various sequences were mapped out and sediment isopach maps were produced (wherever possible) as well as an overall geological subcrop map of the study area. 150 kilometres of shallow penetration Edo Western seismic records acquired off the Sodwana Bay continental shelf were interpreted. Two sediment types are recognised, namely consolidated beach rock/aeolianite and unconsolidated Quaternary shelf sand/bioclastic reef derived sediment. In places, accumulations of bioclastic sediment in subaqueous dune troughs which have been subsequently buried by migrating bedforms manifest themselves on seismic records as dark semi-continuous reflectors beneath the migrating bedform. Close inshore, seismic records show prominent reflectors interpreted as consolidated sediment beneath varying thicknesses of unconsolidated sediment. Close to the shelf break (occurring at approximately -60m), seismic interpretation indicates that thin beach rock developments perch directly upon unconsolidated shelf sand, with the beach rock having been eroded through in places to expose unconsolidated sediment beneath. A sediment thickness map for this area was compiled from the seismic data. The limited penetration of the Pinger system necessitated "greater-than" values being used in many areas. Greatest sediment thicknesses occur in subaqueous dune fields where unconsolidated sediment thickness is at least 11 m. In inshore areas absent of subaqueous dune fields, sediment thicknesses are typically low, varying between 1 and 3m. A prominent submerged dune ridge close inshore limits substantial unconsolidated sediment build-up to landward of this feature. On the seaward side substantial build-up is limited by the action of the Agulhas Current which is actively transporting sediment into the head of submarine canyons which incise the continental shelf at Sodwana Bay. This study shows that on the northern KwaZulu-Natal continental shelf where there is a dearth of unconsolidated Quaternary sediment, the Edo Western seismic system is a useful tool for discerning thin veneers of unconsolidated sediment less than 4m thick. When considering the overall low volumes of unconsolidated sediment present on the shelf, this hitherto unconsidered volume of sediment constitutes an important part of the shelf sediment budget. Submarine landslide features observed on sparker seismic records are described and discussed. Submarine landslides are present which affect a) Sequences A and B, b) Sequence B only and c) Sequence A only, ages of these sediment failures can thus be inferred as being either post- Late Cretaceous or post- Late Tertiary. Offshore Kosi Bay, submarine landslide features affecting Sequence A are buried by unaffected Sequence B sediments, indicating a post- Late Cretaceous to pre- Late Tertiary age of occurrence. Style of failure tends towards mass flow in those submarine landslides in which Sequence B only sediments are affected, while those in which Sequence A is affected exhibit some slide features indicating a greater degree of internal coherency of these sediments compared to Sequence B. Slope stability analysis of a submarine landslide feature offshore St. Lucia Estuary Mouth indicates the failed sediment mass would have been stable under static conditions and that external dynamic forces such as storm waves or seismic activity would have been necessary to induce failure. It is demonstrated that the Zululand earthquake of 1932 would have exceeded the intensity necessary to induce sediment failure and this event should therefore be considered as a possible cause. Seismic evidence of fluvial incision/subaerial exposure at the boundaries between Sequences A and B and C and E are further evidence of lowered sea-levels probably during the Oligocene and Late Pleistocene. The position of the incision into Sequence C relative the present course of the Mkuze River indicates the possibility that this incision could represent the palaeo-outlet of this river. Seismic expression of 3 submarine canyons in the study area indicate that they are currently undergoing active headward erosion, independent of any direct modern fluvial influence. In the case of Ntabende Canyon, a nearby continental shelf incision postulated to be the palaeo-Mkuze outlet indicates that provision of terrigenous material to this portion of the continental shelf could well have accelerated mass wasting processes within the canyon itself. This submarine canyon could therefore have progressed more rapidly to a relatively mature phase of development. Subsurface structure indicates the lack of any post- Late Tertiary fault features beneath the canyons, thus excluding faults active in post- Late Tertiary times as a developmental factor. It is shown that the overall, external morphology of the KwaZulu-Natal upper continental margin is strongly influenced by seismic stratigraphic relationships, with the main influencing factors being outcrop position of the various sequences and depositional angle of sediments of which a sequence is comprised. External morphology has also been greatly modified in places by mass-wasting processes. It is demonstrated also that relating the observed seismic stratigraphy to onshore geological cross sections is problematic due to the distances involved and lack of confident offshore dates for the seismic sequences observed. Seismic relationships observed contribute to an understanding of relative sea-level movements since the Late Cretaceous and the overall geological evolution of the northern KwaZulu-Natal upper continental margin, details of which are discussed.
The bathymetry, sedimentology and seismic stratigraphy of Lake Sibaya- Northern KwaZulu-Natal.
(1998) Miller, Warwick Richard.; Mason, Tom R.; Watkeys, Michael Keith.
The morphology of Lake Sibaya is a product of an ancient fluvial system that drained a coastal landscape dominated by aeolian processes. The sedimentary processes within the lake are driven by wind generated currents. The dominant sedimentary process is one of lake segmentation, whereby prograding bedforms isolate the lake into smaller water bodies. The prograding bedforms include cuspate forelands and sand spits. The size and mobility of these bedforms is a function of sediment availability and current regime. The bathymetry of Lake Sibaya is discussed, with emphasis on geomorphic features derived from the ancient aeolian landscape as well as features related to modern sedimentary processes. The presence of underwater knickpoints and terraces indicate that lake level fluctuations have been common in Lake Sibaya. It is during lake highstands that large volumes of sand are eroded from aeolian dunes which surround the lake and made available for shoreline progradation. Ancient dune topography is preserved to depths of 20 m below water-level within the lake. Surface sediment distribution maps were compiled from 515 grab samples and thirteen core samples. Fine grained, well sorted, coarse skewed quartz sand comprises the majority of the surface area of the lake floor. Gyttja is the other dominant sediment type and accumulates in palaeovalleys and depressions on the lake floor. Sediment distribution in Lake Sibaya is discussed in terms of modern lacustrine processes as well as inherited sedimentary characteristics. The stratigraphy of the sediments underlying Lake Sibaya was investigated using a Uni-Boom seismic profiling system. Seismic profiles were compiled by identifying acoustically reflective surfaces that show regional development. Thirteen seismic overlays were prepared, and are illustrated as west - east and north - south seismic profiles. Five sequences ranging in age from late Cretaceous to Holocene were identified from the seismic profiles, and are described in terms of sequence stratigraphic principles. The seismic sequences were interpreted within a lithostratigraphic framework and are presented as a series of idealised geological sections. Thirteen sediment cores were collected from the Lake Sibaya area in order to ascertain the accuracy of the stratigraphic interpretation of the seismic records, to investigate reflective horizons identified from seismic records and to collect dateable material. Interpretation of the sediment cores reveals that a proto Lake Sibaya existed on drowned dune topography, during the period ± 43500 BP to ± 25500 BP prior to the Last Glacial Maximum. During the early to mid Holocene the Lake Sibaya site was occupied by a saline lagoon which underwent isolation from the sea ± 5030 BP. Since the mid-Holocene the lake has evolved to totally freshwater conditions and has undergone little sedimentation. The geological evolution of the Lake Sibaya area is discussed in terms of the geometry of the identified seismic sequences, the sedimentary characteristics of these sequences and the radiocarbon dates provided from the sediment cores. Palaeo-environmental conditions during the accumulation of the sedimentary sequences is discussed where fossil remains permit.
Sedimentology, stratigraphy and geological history of part of the northern KwaZulu-Natal coastal dune cordon, South Africa.
(1999) Sudan, Pascal.; Whitmore, Gregory P.; Uken, Ronald.
The northern KwaZulu-Natal coast is backed by a continuous aeolian dune cordon that rises in places, to a height of more than 100 metres and a width of 2 kilometres. This MSc thesis documents the geomorphology of the area, as well as the mineralogical, geochemical and textural variation of nine boreholes within a small part of the coastal dune cordon between Lake Nhlabane and Cape St.-Lucia. The results provide useful constraints on the identification of individual beach and aeolian dune systems, their age relationships and spatial distribution. Aeolian dunes within the coastal dune cordon were studied using aerial photographs and grouped into five dune classes that reflect their relative age. These comprise 1) a system of highly weathered dunes inland of the present coastal dune cordon, that are thought to represent older dune cordons; 2) a system of weathered and reworked dunes located on the most inland portion of the coastal dune cordon; 3) a less altered, large field of linear parallel dunes located in the northern part of the study area; 4) a system of large scale parabolic dunes; and 5) a system of coastal, relatively unweathered small parabolic dunes. Mineralogy, geochemistry, texture and SEM analysis of borehole samples revealed a complex internal structure within the present coastal dune cordon. In the most inland part of the dune cordon, a basal light grey unit (Unit K) presents similar characteristics to the Kosi Bay Formation. This is overlain by Unit A, comprising beach and dune systems, characterised by a very high heavy mineral content. Unit A also forms the basal unit of the central and coastal portions of the dune cordon. Unit B contains a mixture of reworked sediments from Unit A and younger sediments. Aeolian Units D and E form the upper part of the dune cordon. Units D and E were derived from beach - foredune systems and contain a high carbonate bioclast content. All units are interpreted to be derived from immature sediment from the Tugela River and mature sediment from the continental shelf. In the southern part of the study area, an additional unit (Unit C) with unique characteristics has been interpreted as an aeolian deposit reworked from local fluvial sediments. The units identified from their sedimentological characteristics can be directly correlated to the regional dune classes identified from the geomorphology. Luminescence dating of two calcareous dunes was undertaken, revealing that only the sediment of the small coastal parabolic dunes (Dune Class 5, Unit E2) is of Holocene age. The deposition of the large field of linear dunes (Dune Class 3, Unit D2) took place between 15 000 and 11 000 BP, during the marine transgression following the last glaciation. Luminescence dating also indicated that both dunes were subject to at least one major reworking event. A study on the weathering characteristics of the dunes can be used to attribute a relative age to the nine sedimentological units. With the help of sea level curves and the two luminescence dates, the nine units were attributed an approximate absolute age and regrouped into four sediment packages thought to broadly represent four interglacial periods. The three younger packages are attributed to the penultimate interglacial (lower part of Unit A), last interglacial (upper part of Unit A, Units B and C) and "Holocene" interglacial (Units D and E). Hence the northern KwaZulu-Natal coastal dune cordon under study represents a complex stacking of three generations of coastal dune cordons, and appears to be constituted of sediments with age ranging from at least two hundred thousand years ago to present. The oldest sediment package (Unit K), interpreted as the Kosi Bay Formation, and the older dune cordons (Dune Class I) must be older than 200 000 years, which is older than considered by previous studies. The "Holocene" dune cordon (Units D and E) is interpreted as the Sibayi Formation.
The assessment of groundwater quality in rural communities : two case studies from KwaZulu-Natal.
(1998) Sherman, Heidi Michelle.
The health and life expectancy of populations in developing countries is largely determined by the availability of good quality drinking water. Boreholes and springs generally provide water of better microbiological and physical quality than surface water sources, however, they may cause health and aesthetic problems due to chemical constituents dissolved out of the host rock. As part of a pilot study to assess the health-related quality of community water supplies, samples were taken from two Quaternary catchment areas in KwaZulu-Natal. The Umkomazi catchment area is located inland from Amanzimtoti, while the Umfolozi catchment area is located north-east of Ulundi. The geology in these areas is significantly different. The Umkomazi area is predominantly underlain by basement rocks of the Natal Structural and Metamorphic Province, while the Umfolozi area is underlain by sedimentary rocks of the Karoo Supergroup. Geographical information systems (GIS) were used to examine the influence of lithology, rainfall and landuse activities on groundwater quality. Major ion analysis of groundwater samples from the Umkomazi area revealed a linear relationship between borehole and spring concentrations. Dwyka Tillite was found to produce water with the highest concentrations of major ions, while Karoo dolerite produced water with the lowest concentrations of major ions. Samples from basement rocks and Natal Group contained intermediate concentrations of major ions. In the Umfolozi area Karoo dolerite samples showed the lowest concentrations of major ions, while the Vryheid Formation and Dwyka Tillite produced the highest borehole and spring concentrations, respectively. High salinity levels in sedimentary rocks may be due to marine influence during deposition. Piper diagrams show relative enrichment of major cations and anions and Stiff diagrams showed characteristic patterns. Fluoride is associated with siliceous basement rocks and related to calcium concentrations through the solubility of calcium fluoride. The trace metals, manganese, iron and zinc were found to cause significant aesthetic problems and possibly health problems in sensitive individuals. These constituents are derived from weathering of bedrock and possibly from the corrosion of metal pipes. There is an inverse relationship between mean annual rainfall (MAR) and electrical conductivity (EC), except near the coast where windblown salinity increases with rainfall. Nitrate, ammonium and E. Coli contamination are linked to landuse activities such as occurrence of human and animal excreta near the water source and the proximity of pit latrines. It is recommended that rural communities be educated about the nature and importance of groundwater quality.
Mechanisms of sill and dyke intrusion.
(1994) Kattenhorn, Simon Allen.; Watkeys, Michael Keith.
Mechanisms of sill and dyke intrusion require an understanding of fracture growth,stress distributions and intensities, dilation,intrusion rates, hydraulic pressure,host-rock effects,en echelon fracture arrays,and flow direction. The methods of previous studies have been applied to natural sill and dyke examples of the Karoo Igneous Province in northern Natal . An en echelon array of Jurassic dolerite sills occurs within Permian Ecca sediments along the Mhlatuze River, west of Empangeni. Dolerite emplacement occurred as two intrusive phases. The first phase resulted in thick, . coarse-grained dolerite sills. The second phase produced relatively thinner, fme-grained sills. The intrusion of fmegrained dolerite into older sills is demonstrated by abrupt variations in the whole-rock and mineral geochemistry profiles across the sills. Syn-crystallisation effects such as crystal settling and fractionation, and post-crystallisation hydrothermal activity is also manifested in the mineralogical and geochemical changes across the sills. The fine grained doleriteis associated with xenolithic dolerite which represents a contaminated magma propagation front of the fine-grained dolerite. The higher viscosity of the xenolithic dolerite hindered propagation, and was thus overtaken and engulfedby the mainmagmapulse. Consistent sinistral off setting of sill segments is interpreted to be the result of a fingered sill periphery intruding an en echelon fracture array. Dilation of individual segments, or fingers, occurred simultaneously. Subsequent interaction of near-tip stresses induced inwardly propagating curvature of adjacent segmentsin the array.Resultant linkage has produced a stepped-sill geometry; sill propagation and flow directions were orthogonal to the plane of linkage. The flow direction is confirmed by shape preferred-orientations of acicular mineral grains within the chilled margins of the sills, indicating the direction of flow to be perpendicular to the plane of the en echelon array, and parallel to strike directions of offset surfaces that link adjacent sill segments. Multiple dyke intrusion is examinedat an outcrop of the Rooi Rand Dyke Swarm, along the Pongola River. Individual intrusive episodes are identifiable on the basis of chill-zone relationships. The pattern along the Pongola River suggests that younger intrusive episodes frequently intrude through the centres of older dykes. A three dimensional analysis of en echelon dyke let segments allows a re-construction of the dilation history,and provides an explanation for the development of blunt-ended intrusion segments. Mineral geochemistry anomalies around dyke tips suggests possible facilitation of incipient fracture via decreases in mineral strengths manifested by geochemical changes. A statistical digital analysis of micro-phenocryst orientations within chilled dyke margins is shown to provide a viable method to ascertain magma flow directions within dykes, and may thus be a useful tool for future investigations.
Palaeoenvironments of the Estcourt formation (Beaufort Group), KwaZulu-Natal.
(1997) Green, Dawn.; Watkeys, Michael Keith.; Smith, R.
At present the Karoo Basin covers approximately 20 000 km2. It is a large intracratonic basin which, from Carboniferous to Jurassic times, was infilled with a succession of sediments ranging from glacial deposits to those deposited in warm, equable conditions. The Beaufort Group forms part of this succession, and was deposited in a terrestrial, river dominated environment. The dominant lithologies exposed in the Estcourt region in the KwaZulu-Natal Midlands belong to the lower and middle Beaufort divided by the PermoTriassic boundary. The Permo-Triassic palaeoenvironment in this region is reconstructed using sedimentary profiles combined with the study of the fossil remains discovered in the area, including plant, body, and trace fossils. The lower Beaufort sediments in this region belong to the Estcourt Formation, and the Middle Beaufort sediments to the Belmont Formation. The Estcourt Formation is dominated by a succession of alternating sandstones, siltstones and mudstones, which are interpreted as representing sediments deposited in a fluvial-floodplain environment, which can be divided into two sub-environments. The first is dominated by sediments that were deposited by meandering rivers on a semi-arid floodplain, and the second sub-environment is represented by those sediments deposited in lacustrine environments. Both of these subenvironments are closely linked and alternate in the rock record indicating many episodes of transgressive-regressive lacustrine episodes. The Estcourt Formation can be closely correlated with the lower Beaufort sediments mapped in other regions of the Karoo Basin, indicating similar climatic and environmental controls throughout the Karoo Basin of southern Africa. The Estcourt Formation also contains a wide variety of body and trace fossils. The PermoTriassic boundary can be traced along the western border of Estcourt by using the distribution pattern of the two mammal-like reptiles Dicynodon and Lystrosaurus. There is evidence of an overlap in the distribution between these to mammal-like reptiles, which together with palaeoflora evidence, indicates that Lystrosaurus evolved during the Late Permian and not Early Triassic as previously thought. The first Triassic sediments are represented in the Estcourt region by a series of maroon shales which can be correlated with the Palingkloof Member.
The petrology and geochemistry of the Merensky reef in the Rustenburg area.
(1994) Brown, Raylan Talbot.; Lee, C. A.; Wilson, Allan H.
Four Merensky reef underground exposures of different reef thickness, representative of the lithological variations exposed in mining, have been drilled and mapped. The relationship of the Merensky reef to the underlying rocks is paraconformable, and a broad-based definition of the highly variable Merensky reef, on the basis of detailed mine-wide mapping, is presented. Fifty two whole-rock samples from one drill intersection were analysed for major and trace elements by X-Ray Fluorescence spectrometry, and for platinum-group elements (PGE) by Neutron Activation analysis. The remaining three drill intersections were analysed for trace elements, and for PGE in one instance. Orthopyroxene and plagioclase mineral separates from one intersection were analysed for major elements by XRF, and the mineral compositions determined. The results of the whole-rock and silicate mineral chemistry are presented and discussed. Whole-rock geochemistry is controlled by modal composition, as are most trace elements. Incompatible elements such as Nb, Zr, Ba, Y and Rb occur in elevated abundances in the feldspathic pyroxenites and show systematic low-correlation relationships with Cu, Ni, Sand the PGE. These patterns are ascribed to the pore space competition between incompatible element enriched silicate melt and sulphide melt. The PGE are systematically associated with the base metal sulphide elements, with some localised decoupling, with Pd and Au showing the greatest chalcophile nature. The other PGE are highly correlated. Deviations in the geochemistry relative to the mode are analysed and discussed. Orthopyroxene and plagioclase mineral compositions consistently define three-way lithological associations, demonstrating limited geochemical relationship between the lithologies. These lithologies represent the footwall and hangingwall norites/anorthosites and the Merensky reef/Merensky pyroxenite sequence. The Merensky reef pegmatoid and the overlying Merensky pyroxenite have more evolved Mg# and Ca# than the norite or anorthosite. Ni in orthopyroxene correlates with whole-rock Ni, providing evidence of re-equilibration. A systematic relationship exists between plagioclase and orthopyroxene mineral compositions, with Ti in both phases defining primary and re-equilibrated trends. Apart from the elevated PGE abundances in the Merensky reef, the Merensky reef and overlying Merensky pyroxenite are geochemically indistinguishable. Certain evolved element distribution patterns coincide with the zone of elevated PGE, Cu and Ni abundances. Abundant geochemical evidence is consistent with late-stage in situ hydromagmatic alteration and modification to the Merensky reef, and in part, the Merensky pyroxenite. In contrast, the texturally similar footwall and hangingwall norites show very little evidence of hydromagmatic effects, where magmatic and submagmatic processes are well preserved. The whole-rock and mineral geochemistry defines and characterises the Merensky succession and provides certain constraints for petrogenetic modelling. A multi-stage process is envisaged for the petrogenesis and evolution of the Merensky succession, involving, 1) a magmatic stage, 2) a submagmatic stage, and 3) a hydromagmatic stage.
The geology and geochemistry of the Rooi Rand Dyke Swarm.
(1996) Meth, Deanna Lorrine.; Watkeys, Michael Keith.
The Jurassic Rooi Rand dolerite dyke swarm was emplaced sub-parallel to the Lebombo Monocline during the initial stages of Gondwana breakup. The dykes extend northwards from the southern Lebombo region in northern KwaZulu-Natal, into central Swaziland, spanning a distance of approximately 200 kilometres with a width between 10 and 22 kilometres. Detailed mapping of a 600m-Iong section on the Pongolo River, established at least eleven phases of intrusion. Each dyke age was systematically sampled and analysed for whole-rock major, trace and rare earth element composition, as well as mineral chemistry. Selected samples were analysed for stable isotopes. In addition to notable intra-dyke chemical variations, there is also a high degree of inter-dyke mineralogical and geochemical variation, each dyke age bearing distinct geochemical characteristics. The apparent geochemical trend is not one of simple fractionation with time. Dyke chemistries are closely linked to magma genesis and magma volumes with time. Evolution of the magmas may be described in terms of varying degrees of partial melting and fractional crystallization, with a small degree of crustal contamination. Major, trace and rare earth element data indicate a lithospheric mantle source for the majority of dyke phases, and an asthenospheric source for only two of the eleven ages. Contrary to this, isotopic data (oxygen and radiogenic) indicate an enriched asthenospheric source for all the dolerites. This suggests that all ages may have originally been derived from the asthenosphere, with the majority of ages being intruded into the lithospheric mantle to later undergo partial melting and fractional crystallization, with some contamination. Previous studies assumed an asthenospheric source with depleted MORB-like rare earth element profiles to be representative for the majority of Rooi Rand dolerites. The Rooi Rand dolerites appear to display a geochemical link with the southern Sabie River Basalt Formation, as well as the Lebombo rhyolites. Magmatic evolution of the dykes was intimately linked to the initial rifting processes of lithospheric stretching and asthenospheric upwelling, which in this case concluded in a classic failed rift situation.
The stratigraphy of the Natal Group.
(1994) Marshall, C. G. A.; Von Brunn, Victor.
Research for this project involved the first systematic field and laboratory investigation over the entire known portion of the Natal Group depositional basin, from just north of Hlabisa in the north, to Hibberdene in the south, and, on a reconnaissance basis, as far south as the Mtamvuna River near Port Edward. The development of a stratigraphy for the Natal Group is traced through the work of previous researchers, who worked in specific areas. The SACS compilation was inadequate, and this unsatisfactory situation was addressed in presenting the first workable stratigraphic subdivision of the Natal Group for the whole of the basin. There are two proposed formations, each representing a cycle of sedimentation - a lower Durban Formation and an upper Mariannhill Formation. These are subdivided into the Ulundi, Eshowe, Kranskloof, Situndu and Dassenhoek Members, and the Tulini, Newspaper and Westville Members, respectively. They are generally greyish red in colour, and consist of conglomerates, sandstones, siltstones and shales. The generally accepted correlation between the Natal Group in KwaZulu-Natal and what was hitherto considered as its time-equivalent in Pondoland has been disproved. Consequently, the supposed interdigitation/transition between these two assemblages, along with the hypothesis that the Kranskloof and Dassenhoek quartz-arenite Members were littoral deposits formed during a marine transgression/regression cycle, is no longer accepted. A provenance to the northeast is proposed, based on palaeocurrent data. Pan-African mountain-building in what is now Mozambique provided molasse sediments which were laid down in an elongate (NE - SW) foreland graben basin. The age of this was determined as 490 Ma, from 4°Ar;J9Ar step-heating on micas extracted from argillaceous samples. Contemporaneous volcanism, as reflected in the presence of volcanic glass (sericitised) shards, is reported. The Natal Group is a molasse deposit, derived some 490 Ma ago from a Pan African orogenic event in southern Mozambique, and deposited in a foreland graben, the Natal Trough, during continued subsidence. Activity of this trough is seen to have continued from Pan African to Permian times. This assemblage rests on the basement, and is overlain by the Dwyka Group. Only part of the basin survives on the African continent, the unknown portion being removed during the fragmentation of Gondwana. The southern limit of the Natal Group is at the Dweshula High, near Port Shepstone, which, together with basin tilting, is seen to have been instrumental in causing the deposition of this assemblage. It is suggested that fluvial activity and debris flow processes led to the deposition of the conglomerates of the Ulundi, Tulini and Westville Members, whereas braided rivers of the Platte and Bijou Creek types deposited the arenaceous and argillaceous sediments which now constitute the other members. The climate was probably semi arid, with ephemeral streams. Shape parameters of the conglomerate clasts point to a fluvial environment. The dividing-line between monomict (quartz) Facies A to the south, and polymict Facies B to the north, of the Tulini Member, was found to coincide with the edge of the craton in this area. The common occurrence of pressure solution phenomena is described. The tensile strength of fractured quartzite clasts in the Ulundi Member is used to estimate a minimum thickness for the Natal Group of 1300 to 2600 m - considerably greater than the present thickness. This estimate supports the hypothesis that much of the Natal Group was removed by erosion during the 200 million year period between the cessation of Natal Group deposition and the onset of Dwyka glaciation, and indeed, by the glaciation itself. The Westville. Member is thus seen as the basal unit of a third cycle of sedimentation, all of which, except the remnants of the Westville Member, have been eroded away.
Assessment of the permeability of Vryheid formation sediments.
(1994) Venter, Bernardus Jacobus.; Jermy, Colin A.
Permeability is that physical property of a porous medium that controls the flow of fluids through that medium. The flow of methane and water may be induced by the excavation of a mine opening in methane-bearing strata. Methane flow into a mine opening constitutes one of the biggest hazards in the coal mining industry. It is poisonous to humans and can ignite at concentrations as low as 5 % per volume and create explosions in the presence of coal dust from mining. If the flow of methane and/or water into the mine opening becomes blocked by an impervious layer, excessive pressures may develop, particularly in the roof strata of the mined seam, which can lead to roof falls. In order to characterize the flow of methane and water into and around the openings in a mine, that was plagued by roof falls suspected of being the result of excessive fluid pressure build-up, a large scale laboratory investigation of the permeability of the roof sediments of the working coal seam in the area was undertaken. The permeability was measured under atmospheric conditions by means of a modified Ohle permeameter, and under triaxial conditions with the aid of a modified Hoek cell. The permeability of the sediments towards methane and water was measured. Nitrogen was used as a control because it is much less reactive than methane towards the sediments used in this project. It was found that the permeability decreases with increasing gas pressure, in the case of gas being the permeating fluid, and increased with increasing water pressure, in the case of water being the permeating fluid. In some instances anomalous plots of permeability versus reciprocal mean gas pressure were obtained. These were attributed to the effects of methane adsorption or the Klinkenberg effect, and a possible method to determine which of the two processes is dominant is discussed. To characterize the flow in the roof strata of the coal seam being mined, the permeability was correlated to fades type. The different fades types were numbered from 1 to 14 with increasing grain size for ease of correlation. Due to the variable nature of the sediments, even in a fades type, no single permeability could be obtained for a fades type. Instead permeability ranges were obtained for each fades type. The definition of the lower and upper limits for each range were found to be dependant on the number of tests done on samples for that fades type. Nonetheless a relationship of increasing permeability with increasing grain size was found in the coarser grained fades (facies type 8 and higher). For the fIner grained fades types the permeability was found to decrease with increase in grain size. A graph could be constructed for use in predicting possible hazardous zones by identifying the fades type and then reading the permeability range that can be expected off the graph. Due to the variable nature of the sediments, the graph is, at this time, only applicable to the areas where the samples were obtained. A permeability prediction graph for all localities would be an ideal but is beyond the scope of this project. Such a graph, and the methods discussed have a wide range of applications in the coal mining and methane gas exploitation industries.

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