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Rhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.

dc.contributor.authorHadebe, Siphamandla Wiseman.
dc.date.accessioned2010-09-07T09:48:34Z
dc.date.available2010-09-07T09:48:34Z
dc.date.issued2008
dc.descriptionThesis (Ph.D.) - University of KwaZulu-Natal, Pietermaritzburg, 2008.en_US
dc.description.abstractThis study has shown that alkythioboranes 1,3,2-dithiaborolane and 1,3,2-dithiaborinane, disproportionated significantly during their synthesis. Their interaction with 1-octene has been investigated, and the rate constants, enthalpies and entropies of the hydroboration process, have been determined. The thermodynamic and kinetic parameters obtained have shown that the hydroboration reaction is sluggish and proceeded via an associative mechanism.
dc.identifier.urihttp://hdl.handle.net/10413/954
dc.language.isoenen_US
dc.subjectHeterocyclic compounds.en_US
dc.subjectBoranes.en_US
dc.subjectOlefins.en_US
dc.subjectTheses--Chemistry.en_US
dc.titleRhodium-catalyzed and uncatalyzed synthesis of boronate esters and their subsequent utility in the Suzuki realm.en_US
dc.typeThesisen_US

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